Allow specific websites that are blocked by Defender content filtering
Allow specific websites
It's possible to override the blocked category in web content filtering to allow a single site by creating a custom allow indicator policy. Allow indicators to supersede the web content filtering policy.
To define an Allow indicator, follow these steps:
In the Microsoft Defender portal, go to Settings > Endpoints > Indicators > URL/Domain > Add Item.
Enter the domain of the site.
Set the policy action to Allow.
More here:
https://learn.microsoft.com/en-us/defender-endpoint/web-content-filtering